There are definitely levels above where Vanadium is toxic in the USA and it appears in the list of areas targeted for long-term federal clean-up activities. It's a matter of how much over how much area and time.
TOXICOLOGICAL PROFILE FOR VANADIUM
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES
Public Health Service
Agency for Toxic Substances and Disease Registry
https://www.atsdr.cdc.gov/toxprofiles/tp58.pdf
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