Climate nutters, page-242

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    Ok. Now we're getting somewhere.

    If infrared is absorbed by a CO2 molecule, it can either go back towards the earth or into space.


    This is the fundamental point I think we are disagreeing on. If an infrared photon is absorbed by a CO2 molecule, and the CO2 molecule collides with another molecule before it re-emits the photon, the rotational or molecular vibrational energy will be converted to translational energy and therefore heat the atmosphere.

    In the lower atmosphere especially, where the mean time between collisions is less than the absorption and re-emission time, this means that the atmosphere is heated slightly more during the day when there are more greenhouse gases in the atmosphere. The atmosphere is transparent enough that heaps of IR radiation makes it to the surface. Hell, even heaps of THz radiation makes it down here from the Sun, and THz is massively absorbed by Earth's atmosphere.

    Is this the major driver for climate change? No, of course not, and I never said it was. This all started when you made an assertion that there was no way CO2 could increase surface temperatures at noon. I said, yes there was and tried to explain the mechanism whereby it does.

    My overarching point is that people misinterpret "1.5 degrees of warming" to mean "45 degree daily peaks are now 46.5 degrees". This is impossible and not supported by data or physics.

    But I never made this point.

    So.. I'm sure that at certain times of day/ air temperatures CO2 could have a slight increase on surface temperatures, but, again, at noon? It would be an interesting set of circumstances.

    From your diagrams, I'm starting to think less that you actually mean noon, but more "noon at a point on the earth's surface which is perpendicular to the incoming solar radiation". So missing big areas of longitude. Is that correct? Either way, I still disagree due to the reasons I described above.

    I don't think that. It certainly absorbs less than at 200k.
    I'd really like to know why you think this about CO2? Which physical effect are you referring to here? Is it Kirchoff's law you're interpreting this way?
 
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