General Renewable Discussion, page-1700

https://whatswatt.com.au/go-with-the-flow-what-are-flow-batteries-and-how-do-they-work

Go with the flow: What are flow batteries, and how do they work?
The Queensland Government’s recently announced Queensland Energy and Jobs Plan commits $500 million to grid-scale and community batteries, including flow batteries, which can be manufactured locally. But what are flow batteries, and how are they different from lithium-ion batteries?

December 14, 2022

Under the Queensland Energy and Jobs Plan, 80 per cent of the electricity used in Queensland is expected to come from renewable sources by 2035. That’s a significant increase on the 21.4 per cent that comes from renewables today.

That means there’ll be a much larger proportion of wind and solar generation in the energy grid. But the output of these generators is variable – it changes depending on the weather and the time of day.

In order for the grid to remain reliable and resilient when the sun isn’t shining and the wind isn’t blowing, these variable renewable energy sources need to be firmed up with dispatchable energy sources. These are energy sources that aren’t dependent on the weather, and can be ramped up quickly to cover shortfalls in supply.

A fundamental problem with electricity is that it can’t be captured and stored. But batteries are a way of getting around this problem – they store chemicals that can be converted into electrical energy, through a process known as electrochemistry. This energy can be released almost instantaneously, helping to maintain grid stability at times of peak demand.

That’s why batteries are a key component of the Queensland Energy and Jobs Plan. Under the Plan, the state’s coal-fired power stations will gradually become clean energy hubs. These hubs will be home to large, grid-scale batteries, taking advantage of the existing transmission infrastructure at these sites – Stanwell, for instance, is planning to develop grid-scale batteries near Tarong Power Station and Stanwell Power Station.

Most grid-scale battery systems are lithium-ion (Li-ion) batteries. Originally used primarily for mobile applications like smart phones, tablets and laptops, Li-ion batteries made their way into electric cars in 2008, with the production of the first Tesla Roadster.

Lithium is the lightest metal, and has the highest electrode potential, which means Li-ion batteries generally offer superior energy-to-weight performance. For this reason, they’re used in most electric car makes and models.

This means that Li-ion batteries are being manufactured in ever-increasing numbers at ever-diminishing prices, which has made them an increasingly economical option for grid-scale energy storage and home energy storage alike.

But as well as Li-ion batteries, the Queensland Energy and Jobs Plan also commits funding to flow battery technologies, which can be made in Queensland with locally sourced minerals.

So, what does that mean, exactly?

What is a flow battery?
Flow batteries are a new entrant into the storage market with a unique design.


The more widespread Li-ion batteries encase all three of their main components – an anode, a cathode, and a chemical solution called an electrolyte that allows for the flow of electrical charge between them – in one cell. A Li-ion battery can contain one of these cells, or it can contain several, but the key is that all three components of each cell are encased together.

Flow batteries, however, are separated into two tanks of liquid electrolyte – one tank of positively charged electrolyte, and one tank of negatively charged electrolyte. A conductive membrane sits between the two storage tanks. When the battery turns on, positive and negative electrons flow back and forth through the membrane, and as they circulate, they generate electricity.

The amount of electricity a flow battery can generate depends on the size of the tanks, so if you need to scale up and store more energy, you can swap them out for bigger tanks, without replacing the membrane.

There are already various types of flow batteries on the market. The difference between them is mostly in the materials that are used to make the electrolyte mixes – vanadium, a material primarily mined in China and Russia, is commonly used, while Australian company Redflow uses a zinc bromine electrolyte mix.

In Queensland, construction has begun in Maryborough on Australia’s first large-scale flow battery manufacturing centre. The $70 million facility, which is being developed by Energy Storage Industries – Asia Pacific (ESI), will manufacture iron flow batteries.

The electrolyte in iron flow batteries is a mix of three abundant and inexpensive materials – iron, salt and water.

What’s the difference between a flow battery and a lithium-ion battery?
Aside from their design, there are some important practical differences between flow batteries and Li-ion batteries.

Whereas grid-scale Li-ion batteries can usually only supply electricity to the grid for a maximum of four hours, flow batteries offer a longer duration. ESS, the Oregon-based company that developed the iron flow battery technology, says its batteries can supply electricity to the grid for up to 12 hours at a time.

On the other hand, flow batteries tend to have much less power density than Li-ion batteries – so while flow batteries can deliver a consistent amount of energy for a longer period of time, Li-ion batteries are better suited to providing larger bursts of energy for shorter periods of time.

Because flow batteries have a lower energy density than Li-ion batteries, they aren’t appropriate for use in electric vehicles. On the other hand, the sheer number of applications that Li-ion batteries are suited to, including electric vehicles, has allowed costs to come down and manufacturing efficiencies to develop as Li-ion batteries have become more common over time.

Flow batteries don’t have a comparable commercial track record, although iron flow batteries, with their cheap and abundant materials, may help to bridge the gap.

Flow batteries are expected to have a longer service life than Li-ion batteries. ESS says its iron flow systems have a 25-year service life, whereas most Li-ion batteries last about 7-to-10 years.

And because flow batteries store their energy in a non-flammable liquid electrolyte in exterior tanks, they are generally considered to be safer than Li-ion batteries, in which all of the components are stored together.

However, those exterior tanks also mean that flow batteries tend to take up more space than Li-ion batteries, which are lighter and more portable. Not only are the tanks themselves sizable, but they have pumps, piping and cooling systems that require more maintenance than self-contained Li-ion batteries.

Ultimately, there won’t be one magic bullet – or, in this case, magic battery – that fulfills every energy storage need.

The Maryborough iron flow battery manufacturing facility sits alongside a suite of announcements, including Stanwell’s aforementioned battery storage systems, a $15 million commitment to scale up Brisbane’s National Battery Testing Centre, and $5 million to finalise and release a Queensland Battery Strategy later this year.

Even then, Li-ion and flow batteries alone won’t provide all of the firming the grid needs – but alongside other energy storage technologies, like large-scale pumped hydro, they can help to allow more wind and solar power to be connected to the grid, and ensure Queenslanders are provided with clean, reliable and affordable power for generations to come.