"fd" likely stands for "field duplicate" in the spot pXRF table[see link]. Field duplicates are samples collected from the same location as the original sample to assess the variability of the analytes at that location. Collecting field duplicates is a standard quality control measure in JORC compliant sampling and analysis to ensure the reliability and reproducibility of the assay results.
https://www.jorc.org/docs/jorc_code_table_1_report_template_updated.docx
significance here?
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