There are also alternatives to using KMnO4 (as I learnt recently)
I'd actually have expected MnO2 to ppt here.. as you're in an oxidizing environment.
But yeah.. also very acidic.. so never know where the sledgehammer metallurgy will get you.. you can remove all sort of species as meta-stable compounds
But then you have peroxides, chlorates, perchloric, hyperchlorous, etc.. lots of tools in the tool box anwyay
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