Allens - I can't say I know what ASX's position is on reporting grades and intercepts based on Xrf results, but I do know that Cobre (CBE) have reported Xrf based results from 5 recent drillholes at their Grammer discovery in Botswana (they are currently waiting on proper lab results). They cut grooves down the side of the core samples so did not just rely on core surface readings. Looks like ASX does allow it.
This is not intended to cross promote - I post the detail because it's relevant.
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