With adequate roof-top solar and an EV, there will be no CO2 generated (ignoring the CO2 use to produced the solar panels and the EV).
Let's sell the EV and buy an ICE vehicle. Now, all the electricity generated from the solar panels can be put into the grid, thereby reducing CO2 emissions by "one car's worth". The ICE will produces CO2 emission by "one's cars worth". Net result is no CO2 generation.
Both scenarios produce the same amount of CO2.
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