Leaching of vanadium and other metals from Athabasca Oil Sands coke and coke ash
Flexicoker coke derived from Athabasca Oil Sands bitumen contains a number of heavy metals, including vanadium, nickel, iron and titanium, which are susceptible to extraction by hydrometallurgical procedures. The leaching behaviour has been studied as a function of pH, temperature and the presence of salts and redox agents. Greater than 50% extraction of the vanadium, iron and nickel can be achieved by acid leaches, but only about 20% of the titanium can be extracted. Weakly acidic leaches extract about 30% of the nickel content but no significant amounts of the other metals. If cokes derived from Athabasca Oil Sands bitumen by the flexicoking process or the conventional delayed-coker coking process are combusted at temperatures below 500 °C, the vanadium and nickel values in the residual ash are readily susceptible to acid leaching.
https://www.sciencedirect.com/science/article/abs/pii/0016236179900085
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