https://en.wikipedia.org/wiki/Pegmatite
Most pegmatites are thought to form from the last fluid fraction of a large crystallizing magma body. This residual fluid is highly enriched in volatiles and trace elements, and its very low viscosity allows molecules to migrate rapidly to join an existing crystal rather than coming together to form new crystals. This allows a few very large crystals to form. While most pegmatites have a simple composition of minerals common in ordinary igneous rock, a few pegmatites have a complex composition, with numerous unusual minerals of rare elements. These complex pegmatites are mined for lithium, beryllium, boron, fluorine, tin, tantalum, niobium, rare earth elements, uranium, and other valuable commodities.
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