Volatile and black oil fluid characteristics
The petroleum fluid spectrum is gradational. There is no strict definition of volatile and black oils; there are only general guidelines and characteristics. Despite this lack of precision and the occasional confusion it brings, classification is quite useful and popular.
Molecular weight is a useful yardstick. Black oils typically range from 70 to 150 in molecular weight but may range as high as 190 to 210. In contrast, volatile oils are lower in molecular weight than black oils and typically range from 43 to 70. Oils with molecular weights greater than 210 usually are classified as heavy oils. Fluids with molecular weights of less than 43 are generally gases, which include gas condensates, wet gases, and dry gases. A molecular weight of 43 marks the lower molecular-weight limit of volatile oils.
Black and volatile oils are sometimes subdivided into different fluid types. For instance, volatile oils include near-critical fluids and high-shrinkage oils. Near-critical fluids represent light volatile oils and can include some very rich condensates. High-shrinkage oils represent the high-molecular-weight end of volatile oils and can include some light black oils.
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