Boosting the Efficiency of Perovskite Solar Cells with CsBr-Modified Mesoporous TiO2 Beads as Electron-Selective Contact
Authors
Ji-Youn Seo,
Ryusuke Uchida,
Hui-Seon Kim,
Yasemin Saygili,
Jingshan Luo,
Chris Moore,
Julie Kerrod,
Anthony Wagstaff,
Mike Eklund, Robert McIntyre,
Norman Pellet,
Shaik M. Zakeeruddin,
Anders Hagfeldt, Michael Grätzel
First published: 20 December 2017Full publication history
DOI: 10.1002/adfm.201705763 View/save citation
Cited by (CrossRef): 0 articles Check for updates Citation tools
Abstract
Rapid extraction of photogenerated charge carriers is essential to achieve high efficiencies with perovskite solar cells (PSCs). Here, a new mesoscopic architecture as electron-selective contact for PSCs featuring 40 nm sized TiO2 beads endowed with mesopores of a few nanometer diameters is introduced. The bimodal pore distribution inherent to these films produces a very large contact area of 200 m2 g−1 whose access by the perovskite light absorber is facilitated by the interstitial voids between the particles. Modification of the TiO2 surface by CsBr further strengthens its interaction with the perovskite. As a result, photogenerated electrons are extracted rapidly producing a very high fill factor of close to 80% a VOC of 1.14 V and a PCE up to 21% with negligible hysteresis.
