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Cobalt pricing breaking out, page-38

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    Hi Aussie_Boy

    Been busy and also had computer problems that wiped a near complete reply.

    One of the main reasons I suspect contamination is the sudden change from sub 100ppm Co in the Esso/Analab portion of PP009 to a fortuitous 4-10 time increase consistently through to 358m where there is another step up in grade. This post has copies of the original assay results for hole 9 which are also tabulated below.

    Column 1 Column 2 Column 3 Column 4 Column 5 Column 6 Column 7
    0 SELECTED ASSAY RESULTS PP009    
    1 ESSO FROM-TO GRADE CO PPM   ACM FROM-TO GRADE CO PPM   ACM 1m REPEATS 358-368
    2 DIAMOND     119-129
    45 RC  
    3 260-265 45   129-139 50 RC  
    4 265-270 55   139-147 END RC 50 RC  
    5 270-275 45          
    6 275-EOH 278 NOT IN REPORT   278-288 505 MINLABS  
    7       288-298 195    
    8       298-308 175    
    9 ANALABS     308-318 340    
    10       298-348 175-975    
    11       348-358 220    
    12       358-368 3350   ALL <5
    13       368-378 3250    
    14       378-388 2400    


    Combine this with the second batch of Minlab assays on the 1m samples giving below detection (which is also suspect) my conclusion is that contamination and/or lab error of some form has crept in.

    The same step change happens between batches of assays for PP011.

    Where 10m RC composites range between 10-45 ppm Co from 0-150m (Minlab Ref No. 83/444) and then for 150-240m (Ref. No. 83/466) the first two 10m composite assays are 445 and 340 ppm Co followed by the 80m at ~0.7% Co.


    I doubt the drilling process would put in enough Co from even highly abrasive lithologies which these may not be.
    Grasping at straws on the drilling end the drillers may have used the wrong type of bit. For soft rock they use bits with diamonds set in a harder matrix and the reverse for hard rocks (diamonds set in a soft matrix that wears away more quickly exposing the diamonds to do the cutting - actually quite a complex art that requires a competent driller with a range of bits).

    IMO one of the most likely areas of contamination could have been the diamond saw (if used) cutting done to create the 10m composites. Again the amount that comes off a saw blade is unlikely to give the levels encountered.

    Another possibility could have been the type of crushing and pulverising equipment used at the lab. The crushing of a 10m composite could have required different equipment than the later 1m samples at Minlabs.

    Other possibilities are drilling chemicals, lubricants in the compositing process, alternating samples from another project, laboratory stuff ups, typo? - transposing say Phosphorous for Cobalt . There may be other possibilities of contamination etc I haven't thought of. Murphy's law - if it can happen it will sooner or later.

    None of the above readily explain the chemical patterns seen in the assays. I suspect there is a problem with the batch of high grade assays (Job Ref 83/466) but why there should be an order of magnitude increase down hole to a max of 1.47% Co is mysterious. Riva have given this lots more thought and decided to drill next month.

    The results of this drilling will probably not explain why the assay results were conflicting as that is an academic question that while interesting won't matter then. For now:

    Low Co in 2017 will indicate contamination or a lab issue of some form happened in 1983 for one batch of assays.

    High results will probably mean Minlabs made some major error with the 1m assays and perhaps the boundary between Esso and ACM at 278m in PP009 is a 'by chance?' major geochemical break.
    However, what are the chances of this happening in PP011 also? Either a very good or a very bad coincidence.

    GLTAH DYOR
 
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