Your metallurgy is sound, but you should brush up on your geology/mineralogy. The correction should be the tin tungsten are concentrated (not extracted) by wet magnetic separation as the Sn/W are hosted in the Zinn. These elements, along with Lithium, are one of the last things to crystallise from melt and end up in the zinnwaldite mineral, or mineral matrix.
Important to note that it is difficult to recover tin tungsten from calcines...
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