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    https://www.pnnl.gov/news-media/longer-lasting-sodium-ion-batteries-horizon

    Non-flammable technology

    The new PNNL-developed sodium-ion technology uses a naturally fire-extinguishing solution that is
    also impervious to temperature changes and can operate at high voltages. One key to this feature is
    the ultra-thin protective layer that forms on the anode. This ultra-thin layer remains stable once
    formed, providing the long cycle life reported in the research article.
    This vial of clear, sodium-ion electrolyte provides the circulating “blood” that keeps the energy flowing
    through an experimental battery technology. (Photo by Andrea Starr | Pacific Northwest National
    Laboratory)
    “We also measured the production of gas vapor at the cathode,” said Phung Le, a PNNL battery
    chemist and one of the lead authors of the study. “We found very minimal gas production. This
    provides new insights to develop stable electrolyte for sodium-ion batteries that may operate at
    elevated temperatures.”
    For now, the sodium-ion technology still lags behind lithium in energy density. But it has its own
    advantages, such as imperviousness to temperature changes, stability and long cycle life, which are
    valuable for applications of certain light-duty electric vehicles and even grid energy storage in the
    future.
    The research team continues to refine their design. Le noted that the team is experimenting with
    other designs in an effort to reduce—and eventually eliminate—the need to include cobalt, which is
    toxic and expensive if not recovered or recycled.
    In addition to Jin, Le and Zhang, the full PNNL research team included Peiyuan Gao, Yaobin Xu,
    Biwei Xiao, Mark H. Engelhard, Xia Cao, Thanh D. Vo, Jiangtao Hu, Lirong Zhong, Bethany E.
    Matthews, Ran Yi, Chongmin Wang, Xiaolin Li and Jun Liu.
    The study was supported by the Department of Energy’s Office of Energy Efficiency and Renewable
    Energy, Vehicle Technologies Office. Imaging studies were performed at EMSL, the Environmental
    Molecular Sciences Laboratory, a DOE Office of Science User Facility at PNNL sponsored by the
    Office of Biological and Environmental Research

 
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