CFC'S do occur naturally and are emitted from volcanoes. The Ozone hole is scientifically documented as been a result of Mt Erebus eruptions from 1972 to the current day ... this includes both Chlorine and Bromide compounds. The Antarctic atmosphere is so dry during the winter months ( low resistance ) that compounds are easily transported to the lower stratosphere by the intense lows.
Co2 responds as a lag effect of the Natural Climate cycle of Heating and Cooling .
Every living person lined up on the planet - that is 'MAN' - shoulder to shoulder would only fill Los Angeles ..a tiny dot on the globe .
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