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You are describing thermodynamics (the ability for different...

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    You are describing thermodynamics (the ability for different materials to either conduct or insulate heat depending on their thermal properties, I am not sure how easy it is to change thermal properties without changing the material, easier to just use a different material, (air or a vacuum is used in double glazing as it is very poor at transferring heat). Nothing to do with Phase Change. See explanation in my post above.
 
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